SCHEDULED MAINTENANCE:
A new protocol for the asymmetric synthesis of trans-2,6-disubstituted-4-piperidones has been developed using a catalytic enantioselective conjugate addition reaction in combination with a diastereoselective lithiation–substitution sequence; an efficient synthesis of (+)-myrtine has been achieved via this route.
M. G. Pizzuti, A. J. Minnaard and B. L. Feringa, Org. Biomol. Chem., 2008, 6, 3464 DOI: 10.1039/B807575A
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