Issue 4, 2008
From the journal:

Dalton Transactions

The preparation and characterisation of ruthenium cyanovinylidene complexes†‡§

Neil J. Brown,a   Prisca K. Eckert,a   Mark A. Fox,a   Dmitri S. Yufit,a   Judith A. K. Howarda  and  Paul J. Low*a  

* Corresponding authors

a Department of Chemistry, Durham University, South Rd, Durham, UK
E-mail: p.j.low@durham.ac.uk
Fax: +44 191 384 4737
Tel: +44 191 334 2114

Abstract

Reactions of half-sandwich ruthenium metal acetylide complexes with 1-cyano-4-dimethylaminopyridinium salts afford complexes containing mono- or di-cyanovinylidene ligands; the procedure can be adapted to permit the simple synthesis of a cyanoacetylide complex, via the in situ deprotonation of a primary cyanovinylidene complex.

Graphical abstract: The preparation and characterisation of ruthenium cyanovinylidene complexes

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Article information

DOI
https://doi.org/10.1039/B714274A
Article type
Communication
Submitted
18 Sep 2007
Accepted
23 Oct 2007
First published
08 Nov 2007

Dalton Trans., 2008, 433-436

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The preparation and characterisation of ruthenium cyanovinylidene complexes

N. J. Brown, P. K. Eckert, M. A. Fox, D. S. Yufit, J. A. K. Howard and P. J. Low, Dalton Trans., 2008, 433 DOI: 10.1039/B714274A

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