Issue 4, 2008
From the journal:

Dalton Transactions

New bimetallic complexes of late transition metals involving pyrazole-bridged bis N-heterocyclic carbene ligands†‡

Sang-Jin Jeona  and  Robert M. Waymouth*a  

* Corresponding authors

a Department of Chemistry, Stanford University, Stanford, California, USA
E-mail: waymouth@stanford.edu
Fax: +01 650 736 2262
Tel: +01 650 723 4515

Abstract

Bimetallic Ni, Rh, and Ir complexes of pyrazolate biscarbene containing bulky substituents have been synthesized and characterized by X-ray crystallography; the Ni complex dimerizes to a highly congested L2Ni2 structure, whereas the corresponding Rh and Ir complexes form bimetallic LM2 structures.

Graphical abstract: New bimetallic complexes of late transition metals involving pyrazole-bridged bis N-heterocyclic carbene ligands

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Article information

DOI
https://doi.org/10.1039/B715212D
Article type
Communication
Submitted
11 Oct 2007
Accepted
16 Oct 2007
First published
08 Nov 2007

Dalton Trans., 2008, 437-439

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New bimetallic complexes of late transition metals involving pyrazole-bridged bis N-heterocyclic carbene ligands

S. Jeon and R. M. Waymouth, Dalton Trans., 2008, 437 DOI: 10.1039/B715212D

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