Issue 48, 2008
From the journal:

Chemical Communications

Mercury or silver atoms bridging trinuclear titanium imido–nitrido systems†

Avelino Martín,a   Noelia Martínez-Espada,a   Miguel Mena,a   Marta E. G. Mosquera,a   Adrián Pérez-Redondoa  and  Carlos Yélamos*a  

* Corresponding authors

a Departamento de Química Inorgánica, Universidad de Alcalá, Alcalá de Henares-Madrid, Spain
E-mail: carlos.yelamos@uah.es
Fax: +34 91 8854683
Tel: +34 91 8854898

Abstract

The imido–nitrido complex [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)] entraps mercury(II) or silver(I) halides MXn to give cube-type adducts [XnM{(μ3-NH)3Ti3(η5-C5Me5)3(μ3-N)}] which react with alkali metal bis(trimethylsilyl)amide reagents to afford [M2{(μ3-N)n(μ3-NH)2−nTi3(η5-C5Me5)3(μ-NH)(μ3-N)}2] (M = Hg, n = 2; M = Ag, n = 1) where two [Ti3N4] cores are linked by two mercury or silver atoms in a linear geometry.

Graphical abstract: Mercury or silver atoms bridging trinuclear titanium imido–nitrido systems

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Article information

DOI
https://doi.org/10.1039/B814982H
Article type
Communication
Submitted
28 Aug 2008
Accepted
14 Oct 2008
First published
11 Nov 2008

Chem. Commun., 2008, 6561-6563

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Mercury or silver atoms bridging trinuclear titanium imido–nitrido systems

A. Martín, N. Martínez-Espada, M. Mena, M. E. G. Mosquera, A. Pérez-Redondo and C. Yélamos, Chem. Commun., 2008, 6561 DOI: 10.1039/B814982H

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