Issue 48, 2008

Mercury or silver atoms bridging trinuclear titanium imido–nitrido systems

Abstract

The imido–nitrido complex [{Ti(η5-C5Me5)(μ-NH)}33-N)] entraps mercury(II) or silver(I) halides MXn to give cube-type adducts [XnM{(μ3-NH)3Ti35-C5Me5)33-N)}] which react with alkali metal bis(trimethylsilyl)amide reagents to afford [M2{(μ3-N)n3-NH)2−nTi35-C5Me5)3(μ-NH)(μ3-N)}2] (M = Hg, n = 2; M = Ag, n = 1) where two [Ti3N4] cores are linked by two mercury or silver atoms in a linear geometry.

Graphical abstract: Mercury or silver atoms bridging trinuclear titanium imido–nitrido systems

Supplementary files

Article information

Article type
Communication
Submitted
28 Aug 2008
Accepted
14 Oct 2008
First published
11 Nov 2008

Chem. Commun., 2008, 6561-6563

Mercury or silver atoms bridging trinuclear titanium imido–nitrido systems

A. Martín, N. Martínez-Espada, M. Mena, M. E. G. Mosquera, A. Pérez-Redondo and C. Yélamos, Chem. Commun., 2008, 6561 DOI: 10.1039/B814982H

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