Issue 45, 2008
From the journal:

Chemical Communications

The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes

Bao Li,a   Feng-Lei Yang,a   Jun Tao,*a   Osamu Sato,b   Rong-Bin Huanga  and  Lan-Sun Zhenga  

* Corresponding authors

a State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, Xiamen University, Xiamen, People’s Republic of China
E-mail: taojun@xmu.edu.cn

b Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka, Japan

Abstract

The effects of pressure on valence trautomeric transition behavior of two complexes, [{Co(tpa)}2(dhbq)]·(PF6)3 (I·(PF6)3) and [{Co(dpqa)}2(dhbq)]·(PF6)3 (II·(PF6)3) (tpa = tris(2-pyridylmethyl)amine, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine and dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone), in the light of changes of magnetic susceptibilities were investigated; the results show that external pressure makes the SC + ET transition process of the two complexes into a general SC process only.

Graphical abstract: The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes

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Article information

DOI
https://doi.org/10.1039/B814944E
Article type
Communication
Submitted
27 Aug 2008
Accepted
18 Sep 2008
First published
14 Oct 2008

Chem. Commun., 2008, 6019-6021

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The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes

B. Li, F. Yang, J. Tao, O. Sato, R. Huang and L. Zheng, Chem. Commun., 2008, 6019 DOI: 10.1039/B814944E

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