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Issue 41, 2008
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Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes: coupling of Ti[double bond, length as m-dash]NNPh2 with PhCCMe, PhCCH, MeCN and tBuCP

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Abstract

The first structurally authenticated [2+2] cycloaddition products of any transition metal hydrazide complexes are reported; cycloaddition products of transition metal hydrazides with alkynes and heteroalkynes have been obtained for the first time; these are the first structurally authenticated cycloaddition products for any transition metal M[double bond, length as m-dash]NNR2 functional group.

Graphical abstract: Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes: coupling of Ti [[double bond, length as m-dash]] NNPh2 with PhCCMe, PhCCH, MeCN and tBuCP

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Publication details

The article was received on 11 Aug 2008, accepted on 04 Sep 2008 and first published on 23 Sep 2008


Article type: Communication
DOI: 10.1039/B813911C
Citation: Chem. Commun., 2008,0, 5101-5103

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    Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes: coupling of Ti[double bond, length as m-dash]NNPh2 with PhCCMe, PhCCH, MeCN and tBuCP

    J. D. Selby, C. Schulten, A. D. Schwarz, A. Stasch, E. Clot, C. Jones and P. Mountford, Chem. Commun., 2008, 0, 5101
    DOI: 10.1039/B813911C

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