Issue 41, 2008
From the journal:

Chemical Communications

Axial chirality control of troposBIPHEP–Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation†‡

Kohsuke Aikawa,a   Yūki Takabayashi,a   Susumu Kawauchib  and  Koichi Mikami*a  

* Corresponding authors

a Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo, Japan
E-mail: mikami.k.ab@m.titech.ac.jp
Fax: +81 3 5734 2776
Tel: +81 3 5734 2142

b Department of Organic and Polymeric Materials, Tokyo Institute of Technology, Tokyo, Japan

Abstract

Diastereopure troposRh complexes bearing not only BIPHEP but also chiral dienes can be employed as highly enantioselective hydrogenation catalysts for an olefinic substrate.

Graphical abstract: Axial chirality control of troposBIPHEP–Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation

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Article information

DOI
https://doi.org/10.1039/B809683J
Article type
Communication
Submitted
09 Jun 2008
Accepted
14 Aug 2008
First published
30 Sep 2008

Chem. Commun., 2008, 5095-5097

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Axial chirality control of troposBIPHEP–Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation

K. Aikawa, Y. Takabayashi, S. Kawauchi and K. Mikami, Chem. Commun., 2008, 5095 DOI: 10.1039/B809683J

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