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Issue 4, 2008
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Group VI metal aminoborylene complex-catalyzed demercuration reactions of bis(alkynyl)mercurials

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Abstract

The first catalytic application of the Group VI metal borylene complexes [(CO)5M[double bond, length as m-dash]BN(SiMe3)2] involves the demercuration reaction of bis(alkynyl)mercurials, [Hg(C[triple bond, length as m-dash]CR)2], with formation of a series of buta-1,3-diynes.

Graphical abstract: Group VI metal aminoborylene complex-catalyzed demercuration reactions of bis(alkynyl)mercurials

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Publication details

The article was received on 10 Oct 2007, accepted on 12 Nov 2007 and first published on 15 Nov 2007


Article type: Communication
DOI: 10.1039/B715597B
Citation: Chem. Commun., 2008,0, 497-498
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    Group VI metal aminoborylene complex-catalyzed demercuration reactions of bis(alkynyl)mercurials

    L. Apostolico, H. Braunschweig, A. G. Crawford, T. Herbst and D. Rais, Chem. Commun., 2008, 0, 497
    DOI: 10.1039/B715597B

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