Issue 4, 2008
From the journal:

Chemical Communications

Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N3P3Cl6] catalyzed by silylium ions

Yun Zhang,a   Keith Huynh,b   Ian Manners*bc  and  Christopher A. Reed*a  

* Corresponding authors

a Center for S and P Block Chemistry, University of California, Riverside, USA
E-mail: chris.reed@ucr.edu
Fax: +1 951 827 2027
Tel: +1 951 827 5197

b Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Canada

c School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK
E-mail: ian.manners@bristol.ac.uk
Fax: +44 (0)117 929 0509
Tel: +44 (0)117 928 7650

Abstract

The temperature required for ring-opening polymerisation of cyclo-N3P3Cl6 can be dramatically lowered by employing trialkylsilylium carboranes [R3Si(CHB11X11] as catalysts.

Graphical abstract: Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N3P3Cl6] catalyzed by silylium ions

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Article information

DOI
https://doi.org/10.1039/B713933K
Article type
Communication
Submitted
12 Sep 2007
Accepted
21 Nov 2007
First published
11 Dec 2007

Chem. Commun., 2008, 494-496

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Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N3P3Cl6] catalyzed by silylium ions

Y. Zhang, K. Huynh, I. Manners and C. A. Reed, Chem. Commun., 2008, 494 DOI: 10.1039/B713933K

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