Issue 4, 2008
From the journal:

Chemical Communications

Intermolecular Cope-type hydroamination of alkynes using hydrazines†

Pamela H. Cebrowski,a   Jean-Grégoire Roveda,a   Joseph Moran,a   Serge I. Gorelsky‡a  and  André M. Beauchemin*a  

* Corresponding authors

a Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie-Curie, Ottawa, ON, Canada
E-mail: andre.beauchemin@uottawa.ca
Fax: +1 613-562-5170
Tel: +1 613-562-5800, ext. 2245

Abstract

Metal-free, intermolecular hydroaminations are performed upon heating aryl acetylenes and MeNHNH2 at 140 °C, with preferential formation of the linear, “anti-Markovnikov” hydrazones.

Graphical abstract: Intermolecular Cope-type hydroamination of alkynes using hydrazines

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Article information

DOI
https://doi.org/10.1039/B715022A
Article type
Communication
Submitted
01 Oct 2007
Accepted
23 Nov 2007
First published
10 Dec 2007

Chem. Commun., 2008, 492-493

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Intermolecular Cope-type hydroamination of alkynes using hydrazines

P. H. Cebrowski, J. Roveda, J. Moran, S. I. Gorelsky and A. M. Beauchemin, Chem. Commun., 2008, 492 DOI: 10.1039/B715022A

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