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Issue 39, 2008
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Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl)methyl diazoamides: an entry into the β-carboline ring system

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Abstract

The intramolecular metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(TMS)methyl diazoamides proceeds with high conformational control and chemoselectivity to give cyclopropyl derivatives, which rearrange to β-carboline products.

Graphical abstract: Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl)methyl diazoamides: an entry into the β-carboline ring system

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Supplementary files

Article information


Submitted
11 Jun 2008
Accepted
11 Jul 2008
First published
28 Aug 2008

Chem. Commun., 2008, 4837-4839
Article type
Communication

Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl)methyl diazoamides: an entry into the β-carboline ring system

B. Zhang and A. G. H. Wee, Chem. Commun., 2008, 4837
DOI: 10.1039/B809890E

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