Issue 32, 2008
From the journal:

Chemical Communications

Electrochemically and photochemically active Palladium(ii) heterotopic metallacalix[3]arenes†

Miguel A. Galindo,ab   Andrew Houlton,*b   William Clegg,b   Ross W. Harrington,b   José Dobado,a   Francisco Santoyo-Gonzalez,a   Fatima Linares,a   M. Angustias Romero*a  and  Jorge A. R. Navarro*a  

* Corresponding authors

a Departamento de Química Inorgánica y Orgánica, Universidad de Granada, Av. Fuentenueva S/N, 18071, Granada, Spain
E-mail: jarn@ugr.es
Fax: +34 9582 48526
Tel: +34 9582 48093

b Chemical Nanoscience Laboratories, School of Natural Sciences, Newcastle University, Newcastle upon Tyne, UK
E-mail: andrew.houlton@ncl.ac.uk

Abstract

The cyclic trinuclear system, [(en)3Pd3(4,7-phen)3]6+, undergoes a ligand exchange reaction with 5-R-2-hydroxypyrimidine derivatives (HRpymo; R = ethynylferrocene, 5-(dimethylamino)-N-(2-propynyl)-1-naphthalene sulfonamide) to give [(en)3Pd3(4,7-phen)2(Rpymo)]5+, functional supramolecular receptors of mononucleotides.

Graphical abstract: Electrochemically and photochemically active Palladium(ii) heterotopic metallacalix[3]arenes

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Article information

DOI
https://doi.org/10.1039/B805705B
Article type
Communication
Submitted
04 Apr 2008
Accepted
29 Apr 2008
First published
18 Jun 2008

Chem. Commun., 2008, 3735-3737

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Electrochemically and photochemically active Palladium(II) heterotopic metallacalix[3]arenes

M. A. Galindo, A. Houlton, W. Clegg, R. W. Harrington, J. Dobado, F. Santoyo-Gonzalez, F. Linares, M. A. Romero and J. A. R. Navarro, Chem. Commun., 2008, 3735 DOI: 10.1039/B805705B

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