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Issue 1, 2008
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1,2-Addition of trialkylaluminium reagents to N-diphenylphosphinoylketimines in the absence of any additional reagents

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Abstract

Using reactive trialkylaluminium reagents for the 1,2-addition on acetophenone- and benzophenone-derived ketimines, α-trisubstituted amines were obtained in excellent yields up to 99%.

Graphical abstract: 1,2-Addition of trialkylaluminium reagents to N-diphenylphosphinoylketimines in the absence of any additional reagents

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Publication details

The article was received on 13 Sep 2007, accepted on 11 Oct 2007 and first published on 23 Oct 2007


Article type: Communication
DOI: 10.1039/B714161K
Chem. Commun., 2008, 105-107

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    1,2-Addition of trialkylaluminium reagents to N-diphenylphosphinoylketimines in the absence of any additional reagents

    R. Reingruber and S. Bräse, Chem. Commun., 2008, 105
    DOI: 10.1039/B714161K

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