Issue 1, 2008
From the journal:

Chemical Communications

Metal-specific allosteric activation and deactivation of a diamine†

Hayley J. Clayton,a   Lindsay P. Harding,a   John P. Irvine,a   John C. Jeffery,b   T. Riis-Johannessen,b   Andrew P. Laws,a   Craig R. Rice*a  and  Martina Whiteheada  

* Corresponding authors

a Department of Chemical and Biological Sciences, University of Huddersfield, Huddersfield, UK
E-mail: c.r.rice@hud.ac.uk
Fax: (+44)148-447-2182

b School of Chemistry, University of Bristol, Cantocks Close, Bristol, UK

Abstract

The reaction of a potentially tetradentate bis(pyridyl–thiazole) ligand with acetone is allosterically activated upon complexation with Cd(II) but deactivated by reaction with Cu(I), demonstrating metal-specific allosteric controlled reactivity.

Graphical abstract: Metal-specific allosteric activation and deactivation of a diamine

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Article information

DOI
https://doi.org/10.1039/B714256K
Article type
Communication
Submitted
14 Sep 2007
Accepted
07 Nov 2007
First published
15 Nov 2007

Chem. Commun., 2008, 108-110

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Metal-specific allosteric activation and deactivation of a diamine

H. J. Clayton, L. P. Harding, J. P. Irvine, J. C. Jeffery, T. Riis-Johannessen, A. P. Laws, C. R. Rice and M. Whitehead, Chem. Commun., 2008, 108 DOI: 10.1039/B714256K

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