A novel trinuclear Re(i) complex containing 1,3,4-thiadiazole-2,5-dithiolate: structural and spectroscopic properties†
Abstract
In the title complex [SSS(Re(CO)5)3](CF3SO3) (SSS = 1,3,4-thiadiazole-2,5-dithiolate), SSS adopts a two-S/one-N (κ3) coordination form, representing an unprecedented coordination pattern for this