Volume 103, 2007

Copper

Abstract

A highlight in copper(I) chemistry is the observation of transient monocopper(I) nitrene complexes by dissociation of nitrene-bridged dicopper(I) species. Among mixed-valence CuI/II species, a complex containing copper in four different coordination geometries produces nanorod CuO particles on thermolysis. Among many studies of Cu2O2 complexes, the mediation of styrene epoxidation by a (μ-η22-peroxo)CuII2 complex is noteworthy. The unique μ4-1,1,3,3 bridging mode for azide has been found in complexes of copper(II) and cobalt(II).

Article information

Article type
Review Article
First published
18 May 2007

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem., 2007,103, 224-233

Copper

D. W. Smith, Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem., 2007, 103, 224 DOI: 10.1039/B612857M

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