Issue 20, 2007
From the journal:

Dalton Transactions

A ketone oximate based cyclic cationic [NiII4] inverse metallacrown from simultaneous chelation and bridging of two ligands†‡

Debashree Mandal,a   Valerio Bertolasi,b   Guillem Aromíc  and  Debashis Ray*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology, Kharagpur, India
E-mail: dray@chem.iitkgp.ernet.in

b Dipartimento di Chimica e Centro di Strutturistica Diffrattometrica, Universita' di Ferrara, via L. Borsari, 46, 44100 Ferrara, Italy

c Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, Barcelona, Spain

Abstract

The Ni4 inverse metallacrown (NHEt3) [Ni4(bmo)4(Hael)2(ael)2](ClO4)3 [(NHEt3)·1·(ClO4)3], with the inverse 12-MC-4 motif, has been assembled via simultaneous chelation and bridging of butan-2,3-dionemonoxime (Hbmo) and 2-amino ethanol (Hael).

Graphical abstract: A ketone oximate based cyclic cationic [NiII4] inverse metallacrown from simultaneous chelation and bridging of two ligands

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Article information

DOI
https://doi.org/10.1039/B704678M
Article type
Communication
Submitted
28 Mar 2007
Accepted
29 Mar 2007
First published
13 Apr 2007

Dalton Trans., 2007, 1989-1992

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A ketone oximate based cyclic cationic [NiII4] inverse metallacrown from simultaneous chelation and bridging of two ligands

D. Mandal, V. Bertolasi, G. Aromí and D. Ray, Dalton Trans., 2007, 1989 DOI: 10.1039/B704678M

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