Issue 20, 2007
From the journal:

Dalton Transactions

Reversible structural isomerisation in rare thioether complexes of cobalt(ii)—effects of ligand architecture

John Evans,a   William Levason,a   Joanna M. Manning,a   Gillian Reid,*a   Nikolaos Tsoureasa  and  Michael Webstera  

* Corresponding authors

a School of Chemistry, University of Southampton, Highfield, Southampton, UK
E-mail: gr@soton.ac.uk
Fax: +44 (0)23 80593781
Tel: +44(0)23 80593609

Abstract

Rare examples of (high spin) Co(II) complexes with geometrically constrained tetrathioether ligands exhibit a very unusual structural isomerism, switching reversibly between tetrahedral monomers in solution and octahedral chain polymers in the solid; the crystal structures of one polymeric species and a tetrahedral monomer model compound are described.

Graphical abstract: Reversible structural isomerisation in rare thioether complexes of cobalt(ii)—effects of ligand architecture

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Article information

DOI
https://doi.org/10.1039/B702792C
Article type
Communication
Submitted
23 Feb 2007
Accepted
27 Mar 2007
First published
19 Apr 2007

Dalton Trans., 2007, 1986-1988

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Reversible structural isomerisation in rare thioether complexes of cobalt(II)—effects of ligand architecture

J. Evans, W. Levason, J. M. Manning, G. Reid, N. Tsoureas and M. Webster, Dalton Trans., 2007, 1986 DOI: 10.1039/B702792C

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