The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+

Ramamoorthy Boomishankar; Joanne Ledger; Jean-Baptiste Guilbaud; Neil L. Campbell; John Bacsa; Richard Bonar-Law; Yaroslav Z. Khimyak; Alexander Steiner

doi:10.1039/B713847D

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The N-donor stabilised cyclotriphosphazene hexacation [P₃N₃(DMAP)₆]⁶⁺†

Ramamoorthy Boomishankar,^a Joanne Ledger,^a Jean-Baptiste Guilbaud,^a Neil L. Campbell,^b John Bacsa,^a Richard Bonar-Law,^a Yaroslav Z. Khimyak^a and Alexander Steiner*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK
E-mail: a.steiner@liv.ac.uk

^b Centre for Materials Discovery, Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK

Abstract

The cyclotriphosphazene P₃N₃Cl₆ reacts with six equivalents of DMAP (4-(dimethylamino)pyridine) in superheated chloroform to form crystals of composition [P₃N₃(DMAP)₆]Cl₆·19CHCl₃ comprising [P₃N₃(DMAP)₆]⁶⁺ ions, which host five chloride ions in basket-type cavities on either side of the ring and at equatorial positions via tetradentate ortho-H-donor arrangements.

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Article information

DOI: https://doi.org/10.1039/B713847D
Article type: Communication
Submitted: 10 Sep 2007
Accepted: 28 Sep 2007
First published: 10 Oct 2007

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Chem. Commun., 2007, 5152-5154

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The N-donor stabilised cyclotriphosphazene hexacation [P₃N₃(DMAP)₆]⁶⁺

R. Boomishankar, J. Ledger, J. Guilbaud, N. L. Campbell, J. Bacsa, R. Bonar-Law, Y. Z. Khimyak and A. Steiner, Chem. Commun., 2007, 5152 DOI: 10.1039/B713847D

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