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Issue 14, 2007
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Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(I) nitrate reveal cooperativity properties in porous molecular materials

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Abstract

Two single-crystal to single-crystal phase transitions in trans-[Ag(NPI)2](NO3)·2CH3OH (1a), (NPI = N-phenylisonicotinamide) were characterized with X-ray crystallography; the first transition is reversible and arises from a desolvation transition induced by vacuum and generated 1b; the second transition was induced by heat at 140 °C and generated 1c.

Graphical abstract: Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(i) nitrate reveal cooperativity properties in porous molecular materials

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Publication details

The article was received on 13 Nov 2006, accepted on 09 Jan 2007 and first published on 30 Jan 2007


Article type: Communication
DOI: 10.1039/B616502H
Chem. Commun., 2007, 1433-1435

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    Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(I) nitrate reveal cooperativity properties in porous molecular materials

    P. S. Mukherjee, N. Lopez, A. M. Arif, F. Cervantes-Lee and J. C. Noveron, Chem. Commun., 2007, 1433
    DOI: 10.1039/B616502H

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