Can the peroxosuccinate complex in the catalytic cycle of taurine/α-ketoglutarate dioxygenase (TauD) act as an alternative oxidant?

Sam P. de Visser

doi:10.1039/B611273K

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Can the peroxosuccinate complex in the catalytic cycle of taurine/α-ketoglutarate dioxygenase (TauD) act as an alternative oxidant?†

Sam P. de Visser*^a

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* Corresponding authors

^a The Manchester Interdisciplinary Biocenter and the School of Chemical Engineering and Analytical Science, 131 Princess Street, Manchester, UK
E-mail: sam.devisser@manchester.ac.uk
Fax: +44 161 3064399
Tel: +44 161 3064882

Abstract

Density functional theoretical studies on the catalytic properties of the peroxosuccinate intermediate in the catalytic cycle of taurine/α-ketoglutarate dioxygenase suggest that it cannot act as a second oxidant.

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Supplementary files

A detailed methods section, three tables with energies, group spin densities and charges, and two figures with optimized geometries of all structures described in this work. PDF (230K)

Article information

DOI: https://doi.org/10.1039/B611273K
Article type: Communication
Submitted: 04 Aug 2006
Accepted: 29 Sep 2006
First published: 23 Oct 2006

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Chem. Commun., 2007, 171-173

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Can the peroxosuccinate complex in the catalytic cycle of taurine/α-ketoglutarate dioxygenase (TauD) act as an alternative oxidant?

S. P. de Visser, Chem. Commun., 2007, 171 DOI: 10.1039/B611273K

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Chemical Communications

Can the peroxosuccinate complex in the catalytic cycle of taurine/α-ketoglutarate dioxygenase (TauD) act as an alternative oxidant?†

Abstract

Supplementary files

Article information

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Can the peroxosuccinate complex in the catalytic cycle of taurine/α-ketoglutarate dioxygenase (TauD) act as an alternative oxidant?

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