Issue 43, 2007
From the journal:

Chemical Communications

The role of temperature on the structure and dimensionality of MOFs: an illustrative study of the formation of manganese oxy-bis(benzoate) structures†

Partha Mahata,a   A. Sundaresanb  and  Srinivasan Natarajan*a  

* Corresponding authors

a Framework Solids Laboratory, Solid State and Structural Chemistry Unit, Indian Institute of Science, India
E-mail: snatarajan@sscu.iisc.ernet.in
Fax: +91-80-2360-1310

b Chemistry and Physics of Material Unit, Jawaharlal Nehru Centre For Advanced Scientific Research, India

Abstract

Three new manganese oxy-bis(benzoate) compounds, synthesized by increasing the reaction temperature, with increasing dimensionality and decreasing Mn–Mn distances, indicate a possible pathway through an entropy driven dehydration route.

Graphical abstract: The role of temperature on the structure and dimensionality of MOFs: an illustrative study of the formation of manganese oxy-bis(benzoate) structures

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Article information

DOI
https://doi.org/10.1039/B708060C
Article type
Communication
Submitted
30 May 2007
Accepted
08 Aug 2007
First published
20 Aug 2007

Chem. Commun., 2007, 4471-4473

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The role of temperature on the structure and dimensionality of MOFs: an illustrative study of the formation of manganese oxy-bis(benzoate) structures

P. Mahata, A. Sundaresan and S. Natarajan, Chem. Commun., 2007, 4471 DOI: 10.1039/B708060C

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