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Issue 14, 2007
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Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(i) nitrate reveal cooperativity properties in porous molecular materials

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Abstract

Two single-crystal to single-crystal phase transitions in trans-[Ag(NPI)2](NO3)·2CH3OH (1a), (NPI = N-phenylisonicotinamide) were characterized with X-ray crystallography; the first transition is reversible and arises from a desolvation transition induced by vacuum and generated 1b; the second transition was induced by heat at 140 °C and generated 1c.

Graphical abstract: Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(i) nitrate reveal cooperativity properties in porous molecular materials

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Article information


Submitted
13 Nov 2006
Accepted
09 Jan 2007
First published
30 Jan 2007

Chem. Commun., 2007, 1433-1435
Article type
Communication

Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(I) nitrate reveal cooperativity properties in porous molecular materials

P. S. Mukherjee, N. Lopez, A. M. Arif, F. Cervantes-Lee and J. C. Noveron, Chem. Commun., 2007, 1433
DOI: 10.1039/B616502H

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