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Issue 5, 2006
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Combination vs. disproportionation in dialkyl biradicals. Selectivity reversal in a crystalline solid

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Abstract

While 1,6-biradicals produced by photodecarbonylation of dimethyl 11-oxodibenzo[c,h]bicyclo[4.4.1]undeca-3,8-diene-1,6-dicarboxylate (1) react exclusively by disproportionation in benzene solution, reactions in crystals lead to radical–radical combination reactions in almost quantitative yield.

Graphical abstract: Combination vs. disproportionation in dialkyl biradicals. Selectivity reversal in a crystalline solid

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Article information


Submitted
11 Jan 2006
Accepted
31 Mar 2006
First published
18 Apr 2006

Photochem. Photobiol. Sci., 2006,5, 449-451
Article type
Communication

Combination vs. disproportionation in dialkyl biradicals. Selectivity reversal in a crystalline solid

T. Choe, S. I. Khan and M. A. Garcia-Garibay, Photochem. Photobiol. Sci., 2006, 5, 449
DOI: 10.1039/B603909J

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