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Issue 5, 2006
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A novel supported Katsuki-type (salen)Mn complex for asymmetric epoxidation

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Abstract

We have successfully prepared an unsymmetrical analogue of a Katsuki-type salen ligand having a hydroxyalkyl group at the 6-position of just one of the binaphthyl units in the ligand, and also several Mn(III) complexes; these complexes have been attached to a polymer by an ester link and such polymer catalysts have been shown to be highly enantioselective and recoverable catalysts for the epoxidation of 1,2-dihydronaphthalene.

Graphical abstract: A novel supported Katsuki-type (salen)Mn complex for asymmetric epoxidation

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Article information


Submitted
12 Dec 2005
Accepted
20 Jan 2006
First published
01 Feb 2006

Org. Biomol. Chem., 2006,004, 917-927
Article type
Paper

A novel supported Katsuki-type (salen)Mn complex for asymmetric epoxidation

K. Smith, C. Liu and G. A. El-Hiti, Org. Biomol. Chem., 2006, 004, 917
DOI: 10.1039/B517611P

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