Issue 48, 2006
From the journal:

Chemical Communications

Oxovanadium(v)-catalyzed oxidative biaryl synthesis from organoborate under O2†

Hidenori Mizuno,a   Hidehiro Sakurai,a   Toru Amayaa  and  Toshikazu Hirao*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan
E-mail: hirao@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-7415
Tel: +81-6-6879-7413

Abstract

Oxidative ligand coupling of organoborates was catalyzed by VO(OEt)Cl2 under oxygen atmosphere, which provides a versatile method for the selective synthesis of symmetrical or unsymmetrical biaryls.

Graphical abstract: Oxovanadium(v)-catalyzed oxidative biaryl synthesis from organoborate under O2

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Article information

DOI
https://doi.org/10.1039/B610731A
Article type
Communication
Submitted
26 Jul 2006
Accepted
20 Sep 2006
First published
12 Oct 2006

Chem. Commun., 2006, 5042-5044

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Oxovanadium(V)-catalyzed oxidative biaryl synthesis from organoborate under O2

H. Mizuno, H. Sakurai, T. Amaya and T. Hirao, Chem. Commun., 2006, 5042 DOI: 10.1039/B610731A

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