Issue 48, 2006

Enantioselective radical addition reactions to the C[double bond, length as m-dash]N bond utilizing chiral quaternary ammonium salts of hypophosphorous acid in aqueous media

Abstract

An enantioselective addition of alkyl radicals to glyoxylate oxime ether mediated by Cinchona alkaloid derived chiral ammonium salts of hypophosphorous acid, QP and QDP, has been developed.

Graphical abstract: Enantioselective radical addition reactions to the C [[double bond, length as m-dash]] N bond utilizing chiral quaternary ammonium salts of hypophosphorous acid in aqueous media

Article information

Article type
Communication
Submitted
08 Sep 2006
Accepted
21 Sep 2006
First published
12 Oct 2006

Chem. Commun., 2006, 5045-5047

Enantioselective radical addition reactions to the C[double bond, length as m-dash]N bond utilizing chiral quaternary ammonium salts of hypophosphorous acid in aqueous media

D. H. Cho and D. O. Jang, Chem. Commun., 2006, 5045 DOI: 10.1039/B613045C

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