Issue 2, 2006
From the journal:

Chemical Communications

No aromaticity of P64− observed via solid state 31P-NMR spectroscopy†

Florian Kraus,a   Jörn Schmedt auf der Günne,b   Brian F. DiSallea  and  Nikolaus Korber*a  

* Corresponding authors

a Universität Regensburg, Universitätsstrasse 31, 93053 Regensburg, Germany
E-mail: nikolaus.korber@chemie.uni-regensburg.de
Fax: +49 941 9431812
Tel: +49 941 9434448

b Ludwig-Maximilians-Universität, Butenandtstrasse 5-13, 81377 München, Germany
E-mail: gunch@cup.uni-muenchen.de
Fax: +49 89 218077440
Tel: +49 89 218077433

Abstract

The solid state NMR spectra of the binary alkali hexaphosphides Rb4P6 and Cs4P6 unambiguously show the P64− anion not to be aromatic.

Graphical abstract: No aromaticity of P64− observed via solid state 31P-NMR spectroscopy

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Article information

DOI
https://doi.org/10.1039/B513037A
Article type
Communication
Submitted
15 Sep 2005
Accepted
25 Oct 2005
First published
18 Nov 2005

Chem. Commun., 2006, 218-219

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No aromaticity of P64− observed via solid state 31P-NMR spectroscopy

F. Kraus, J. Schmedt auf der Günne, B. F. DiSalle and N. Korber, Chem. Commun., 2006, 218 DOI: 10.1039/B513037A

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