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Issue 7, 2006
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Novel weak coordination to silylium ions: formation of nearly linear Si–H–Si bonds

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Abstract

The weakly coordinating carborane anion in ion-like trialkylsilyl species R3Si(CHB11Cl11) can be displaced by nucleophiles as weak as ortho-dichlorobenzene, SO2 and trialkylsilanes, the latter forming nearly linear hydride bridges in R3Si–H–SiR3+ cations.

Graphical abstract: Novel weak coordination to silylium ions: formation of nearly linear Si–H–Si bonds

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Article information


Submitted
09 Aug 2005
Accepted
01 Dec 2005
First published
05 Jan 2006

Chem. Commun., 2006, 767-769
Article type
Communication

Novel weak coordination to silylium ions: formation of nearly linear Si–H–Si bonds

S. P. Hoffmann, T. Kato, F. S. Tham and C. A. Reed, Chem. Commun., 2006, 767
DOI: 10.1039/B511344J

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