Issue 7, 2006
From the journal:

Chemical Communications

A new method for the synthesis of Z-enediones via IBX-mediated oxidative rearrangement of 2-alkynyl alcohol systems†

Benedikt Cronea  and  Stefan F. Kirsch*a  

* Corresponding authors

a Department Chemie, Technische Universität München, Lichtenbergstr. 4, Garching, Germany
E-mail: stefan.kirsch@ch.tum.de
Fax: +49(89)28913315
Tel: +49(89)28913229

Abstract

o-Iodoxybenzoic acid (IBX) was found to mediate the conversion of α-alkynyl alcohols into Z-enediones under notably mild conditions via a novel rearrangement mechanism (33–65% yield, 13 examples).

Graphical abstract: A new method for the synthesis of Z-enediones via IBX-mediated oxidative rearrangement of 2-alkynyl alcohol systems

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Article information

DOI
https://doi.org/10.1039/B515838A
Article type
Communication
Submitted
09 Nov 2005
Accepted
29 Nov 2005
First published
05 Jan 2006

Chem. Commun., 2006, 764-766

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A new method for the synthesis of Z-enediones via IBX-mediated oxidative rearrangement of 2-alkynyl alcohol systems

B. Crone and S. F. Kirsch, Chem. Commun., 2006, 764 DOI: 10.1039/B515838A

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