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The PCC/SiO2-promoted double oxidation of 3-cyclohexene-1,2-diols, which were easily prepared by the two-step sequence of α′-hydroxylation of various conjugated cyclohexenones and the subsequent nucleophilic carbonyl addition of alkyl anions, produced diversely substituted 1,4-hydrobenzoquinones.

Graphical abstract: Preparation of 1,4-hydrobenzoquinones by the PCC/SiO2-promoted double oxidation of 3-cyclohexene-1,2-diols

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