Issue 19, 2005

Preparation of 1,4-hydrobenzoquinones by the PCC/SiO2-promoted double oxidation of 3-cyclohexene-1,2-diols

Abstract

The PCC/SiO2-promoted double oxidation of 3-cyclohexene-1,2-diols, which were easily prepared by the two-step sequence of α′-hydroxylation of various conjugated cyclohexenones and the subsequent nucleophilic carbonyl addition of alkyl anions, produced diversely substituted 1,4-hydrobenzoquinones.

Graphical abstract: Preparation of 1,4-hydrobenzoquinones by the PCC/SiO2-promoted double oxidation of 3-cyclohexene-1,2-diols

Article information

Article type
Communication
Submitted
03 Aug 2005
Accepted
26 Aug 2005
First published
02 Sep 2005

Org. Biomol. Chem., 2005,3, 3479-3481

Preparation of 1,4-hydrobenzoquinones by the PCC/SiO2-promoted double oxidation of 3-cyclohexene-1,2-diols

H. Jin Kim and S. Koo, Org. Biomol. Chem., 2005, 3, 3479 DOI: 10.1039/B511067J

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