Issue 9, 2005
From the journal:

Organic & Biomolecular Chemistry

Selective synthesis of C-arylglycosides via Cp*RuCl-catalyzed partially intramolecular cyclotrimerizations of C-alkynylglycosides

Yoshihiko Yamamoto,*a   Tomoaki Saigoku,a   Hisao Nishiyama,a   Takashige Ohgaib  and  Kenji Itohb  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, Japan
E-mail: yamamoto@apchem.nagoya-u.ac.jp
Fax: 81 52 789 3209
Tel: 81 52 789 3337

b Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, Japan

Abstract

In the presence of catalytic amounts of Cp*RuCl(cod), the partially intramolecular cyclotrimerizations of various C-alkynylglycosides and C-diynylglycosides proceeded at ambient temperature to afford C-arylglycosides.

Graphical abstract: Selective synthesis of C-arylglycosides via Cp*RuCl-catalyzed partially intramolecular cyclotrimerizations of C-alkynylglycosides

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Article information

DOI
https://doi.org/10.1039/B503258J
Article type
Paper
Submitted
04 Mar 2005
Accepted
21 Mar 2005
First published
07 Apr 2005

Org. Biomol. Chem., 2005,3, 1768-1775

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Selective synthesis of C-arylglycosides via Cp*RuCl-catalyzed partially intramolecular cyclotrimerizations of C-alkynylglycosides

Y. Yamamoto, T. Saigoku, H. Nishiyama, T. Ohgai and K. Itoh, Org. Biomol. Chem., 2005, 3, 1768 DOI: 10.1039/B503258J

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