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Tetrahydroxyfenestrindane undergoes HPF6-catalyzed condensation with anisole, 2-methylanisole and the three dimethoxybenzenes to furnish several centrohexaindanes bearing oxyfunctionalization at the opposite ends of one of the three [2,2′]-spirobiindane axes.

Graphical abstract: Methoxy-substituted centrohexaindanes through the fenestrane route

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