Issue 3, 2005
From the journal:

Dalton Transactions

Homochiral crystallization of helical coordination chains bridged by achiral ligands: can it be controlled by the ligand structure?†

Yong-Tao Wang,a   Ming-Liang Tong,a   Hai-Hua Fan,b   He-Zhou Wangb  and  Xiao-Ming Chen*ab  

* Corresponding authors

a School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou, China
E-mail: cescxm@zsu.edu.cn
Fax: (+86)20-8411-2245
Tel: (+86)20-8411-2074

b State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-Sen University, Guangzhou, China

Abstract

Homochiral/heterochiral crystallizations of helical chiral polymer chains bridged by achiral poly-pyridyl ligands dependent on the structures of the bridging ligands and independent on the solvent are described, implying a possible strategy to design achiral crystals of helical chains using chiral bridging ligands.

Graphical abstract: Homochiral crystallization of helical coordination chains bridged by achiral ligands: can it be controlled by the ligand structure?

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Article information

DOI
https://doi.org/10.1039/B416412A
Article type
Communication
Submitted
27 Oct 2004
Accepted
14 Dec 2004
First published
04 Jan 2005

Dalton Trans., 2005, 424-426

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Homochiral crystallization of helical coordination chains bridged by achiral ligands: can it be controlled by the ligand structure?

Y. Wang, M. Tong, H. Fan, H. Wang and X. Chen, Dalton Trans., 2005, 424 DOI: 10.1039/B416412A

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