Issue 3, 2005
From the journal:

Dalton Transactions

Zirconium and titanium amido complexes with 3,3-dimethyl-1,5-diaza-8-oxacyclodecane; facile C–H activation of the macrocyclic rim†

Robin M. Porter,a   Andreas A. Danopoulos,*a   Gillian Reida  and  Lisa R. Titcomba  

* Corresponding authors

a School of Chemistry, University of Southampton, Highfield, Southampton, Hampshire, UK
E-mail: ad1@soton.ac.uk

Abstract

Reaction of the dilithium salt of 3,3-dimethyl-1,5-diaza-8-oxacyclodecane, [(NLi)2O], with Zr(NEt2)2Cl2(thf)2 gave the formally 20e− complex [Zr(N2O)2]; metallation of the macrocycle [(NH)2O], with Ti(benzyl)4 gave rise to [(N2O)*Ti(benzyl)]2 in which the trianionic diamido (N2O)* was formed by an unprecedented C–H activation of the carbon α to the amido nitrogen.

Graphical abstract: Zirconium and titanium amido complexes with 3,3-dimethyl-1,5-diaza-8-oxacyclodecane; facile C–H activation of the macrocyclic rim

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Article information

DOI
https://doi.org/10.1039/B418431A
Article type
Communication
Submitted
07 Dec 2004
Accepted
15 Dec 2004
First published
04 Jan 2005

Dalton Trans., 2005, 427-428

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Zirconium and titanium amido complexes with 3,3-dimethyl-1,5-diaza-8-oxacyclodecane; facile C–H activation of the macrocyclic rim

R. M. Porter, A. A. Danopoulos, G. Reid and L. R. Titcomb, Dalton Trans., 2005, 427 DOI: 10.1039/B418431A

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