Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 43, 2005
Previous Article Next Article

The unexpected similar second-order NLO response for nearly planar and largely twisted push–pull stilbazole chromophores: EFISH and theoretical TD-DFT evidence

Author affiliations

Abstract

The molecular second-order nonlinear optical properties of planar (E)-4-[2-(4-(N-methyl-N-hexadecylaminophenyl)ethenyl]pyridine (L1) and [cis-Ir(CO)2ClL1] and of the significantly twisted new chromophores (E)-4-[(5,6,7,8-tetrahydro-5-isoquinolylidene)methyl]-N-methyl-N-hexadecylaniline (L2) and [cis-Ir(CO)2ClL2] are reported, evidencing for the first time that planarity of a conventional (donor)(π-bridge)(acceptor) structure is not compulsory to reach a large NLO response.

Graphical abstract: The unexpected similar second-order NLO response for nearly planar and largely twisted push–pull stilbazole chromophores: EFISH and theoretical TD-DFT evidence

Back to tab navigation

Article information


Submitted
30 Jun 2005
Accepted
02 Sep 2005
First published
04 Oct 2005

Chem. Commun., 2005, 5405-5407
Article type
Communication

The unexpected similar second-order NLO response for nearly planar and largely twisted push–pull stilbazole chromophores: EFISH and theoretical TD-DFT evidence

D. Locatelli, S. Quici, D. Roberto and F. De Angelis, Chem. Commun., 2005, 5405
DOI: 10.1039/B509258B

Social activity

Search articles by author

Spotlight

Advertisements