Issue 37, 2005
From the journal:

Chemical Communications

The synthesis of isostructural Mo2+porphyrin and N-confused porphyrin complexes

John D. Harvey,a   Janet L. Shaw,a   Richard S. Herrickb  and  Christopher J. Ziegler*a  

* Corresponding authors

a Department of Chemistry, University of Akron, Akron, OH 44325-3601, USA
E-mail: ziegler@uakron.edu
Fax: +1-(330)972-7370
Tel: +1-(330)972-2531

b Department of Chemistry, College of Holy Cross, Box C, Worcester, MA 01610-2395, USA
E-mail: rherrick@holycross.edu
Fax: +1-(508)793-3530
Tel: +1-(508)793-2490

Abstract

We have synthesized the first early transition metal N-confused porphyrin complex Mo(NCTPP)(pip)2; this species is isostructural to its normal porphyrin analog Mo(TPP)(pip)2 but exhibits significant electronic differences arising from the inversion of a single pyrrolic group.

Graphical abstract: The synthesis of isostructural Mo2+ porphyrin and N-confused porphyrin complexes

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Article information

DOI
https://doi.org/10.1039/B508913A
Article type
Communication
Submitted
22 Jun 2005
Accepted
29 Jul 2005
First published
23 Aug 2005

Chem. Commun., 2005, 4663-4665

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The synthesis of isostructural Mo2+ porphyrin and N-confused porphyrin complexes

J. D. Harvey, J. L. Shaw, R. S. Herrick and C. J. Ziegler, Chem. Commun., 2005, 4663 DOI: 10.1039/B508913A

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