Issue 30, 2005
From the journal:

Chemical Communications

Exclusive transition state stabilization in the supramolecular catalysis of Diels–Alder reaction by a uranyl salophen complex†

Antonella Dalla Cort,a   Luigi Mandolini*a  and  Luca Schiaffinoa  

* Corresponding authors

a Dipartimento di Chimica and IMC-CNR, Università La Sapienza, Box 34, Roma 62, 00185 Roma, Italy
E-mail: luigi.mandolini@uniroma1.it
Fax: +39 06490421
Tel: +39 0649913624

Abstract

Whereas the parent uranyl salophen is catalytically inactive, its phenyl derivative effectively catalyses with turnover the reaction of benzoquinone with 1,3-cyclohexadiene, while showing no appreciable affinity towards reactants and product.

Graphical abstract: Exclusive transition state stabilization in the supramolecular catalysis of Diels–Alder reaction by a uranyl salophen complex

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Article information

DOI
https://doi.org/10.1039/B504713G
Article type
Communication
Submitted
07 Apr 2005
Accepted
07 Jun 2005
First published
01 Jul 2005

Chem. Commun., 2005, 3867-3869

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Exclusive transition state stabilization in the supramolecular catalysis of Diels–Alder reaction by a uranyl salophen complex

A. Dalla Cort, L. Mandolini and L. Schiaffino, Chem. Commun., 2005, 3867 DOI: 10.1039/B504713G

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