Issue 30, 2005
From the journal:

Chemical Communications

A new route to metallacycloalkanes

Katja Dralle,a   Nastassia L. Jaffa,a   Tanya le Roex,a   John R. Moss,*a   Susan Travis,a   Nicholas D. Watermeyera  and  Akella Sivaramakrishnaa  

* Corresponding authors

a Department of Chemistry, University of Cape Town, Rondebosch, South Africa
E-mail: jrm@science.uct.ac.za
Fax: +27 21 689-7499
Tel: +27 21 650-2535

Abstract

Reaction of the bis-alkenyl complex cis-[Pt(PPh3)2(CH2CH2CH[double bond, length as m-dash]CH2)2] with Grubbs 1st generation catalyst gives, in high yield, the metallacycloalkene cis-[Pt(PPh3)2(CH2CH2CH[double bond, length as m-dash]CHCH2CH2)], which can be hydrogenated to the metallacycloalkane cis-[Pt(PPh3)2(CH2)6].

Graphical abstract: A new route to metallacycloalkanes

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Article information

DOI
https://doi.org/10.1039/B504747A
Article type
Communication
Submitted
06 Apr 2005
Accepted
26 May 2005
First published
16 Jun 2005

Chem. Commun., 2005, 3865-3866

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A new route to metallacycloalkanes

K. Dralle, N. L. Jaffa, T. le Roex, J. R. Moss, S. Travis, N. D. Watermeyer and A. Sivaramakrishna, Chem. Commun., 2005, 3865 DOI: 10.1039/B504747A

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