Issue 6, 2005
From the journal:

Chemical Communications

A porphyrin nanochannel: formation of cationic channels by a protonated saddle-distorted porphyrin and its inclusion behavior†

Ryosuke Haradaa  and  Takahiko Kojima*a  

* Corresponding authors

a Department of Chemistry, Faculty of Sciences, Kyushu University, Hakozaki, Higashi-Ku, Fukuoka 812-8581, Japan
E-mail: cosyscc@mbox.nc.kyushu-u.ac.jp
Fax: +81-92-642-2570
Tel: +81-92-642-4179

Abstract

A highly saddle-distorted dodecaphenylporphyrin dication (H4DPP2+) was revealed by X-ray crystallography to form positively charged porphyrin nanochannels which were 1 nm in diameter; chloride anion and redox-active hydroquinone could be incorporated in the channels.

Graphical abstract: A porphyrin nanochannel: formation of cationic channels by a protonated saddle-distorted porphyrin and its inclusion behavior

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Article information

DOI
https://doi.org/10.1039/B414483J
Article type
Communication
Submitted
21 Sep 2004
Accepted
05 Nov 2004
First published
15 Dec 2004

Chem. Commun., 2005, 716-718

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A porphyrin nanochannel: formation of cationic channels by a protonated saddle-distorted porphyrin and its inclusion behavior

R. Harada and T. Kojima, Chem. Commun., 2005, 716 DOI: 10.1039/B414483J

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