Issue 6, 2005

Construction of triangular metallomacrocycles: [M3(1,2-bis(2,2′∶6′,2″-terpyridin-4-yl-ethynyl)benzene)3] [M = Ru(ii), Fe(ii), 2Ru(ii)Fe(ii)]

Abstract

Complexation of a predesigned (1,2-bis(2,2′∶6′,2″-terpyridin-4-yl-ethynyl)benzene) ligand possessing a 60° angle between two terpyridines with transition metals [Fe(II) and Ru(II)] afforded the self-assembled, triangular metallomacrocycles.

Graphical abstract: Construction of triangular metallomacrocycles: [M3(1,2-bis(2,2′∶6′,2″-terpyridin-4-yl-ethynyl)benzene)3] [M = Ru(ii), Fe(ii), 2Ru(ii)Fe(ii)]

Supplementary files

Article information

Article type
Communication
Submitted
18 Jun 2004
Accepted
12 Oct 2004
First published
16 Dec 2004

Chem. Commun., 2005, 713-715

Construction of triangular metallomacrocycles: [M3(1,2-bis(2,2′∶6′,2″-terpyridin-4-yl-ethynyl)benzene)3] [M = Ru(II), Fe(II), 2Ru(II)Fe(II)]

S. Hwang, C. N. Moorefield, F. R. Fronczek, O. Lukoyanova, L. Echegoyen and G. R. Newkome, Chem. Commun., 2005, 713 DOI: 10.1039/B409348H

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