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Issue 16, 2005
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A C2-symmetric nickel diamine complex as an asymmetric catalyst for enecarbamate additions to butane-2,3-dione

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Abstract

Butane-2,3-dione was activated towards nucleophilic addition of enecarbamates by a series of metal triflate complexes of a C2-symmetric diamine to give stereogenic, aldol-like, t-alcohols, a novel nickel(II) triflate complex was identified as a good catalyst for this asymmetric transformation, and an aquo nickel(II) complex was identified by XRD techniques.

Graphical abstract: A C2-symmetric nickel diamine complex as an asymmetric catalyst for enecarbamate additions to butane-2,3-dione

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Article information


Submitted
18 Apr 2005
Accepted
22 Jun 2005
First published
07 Jul 2005

Org. Biomol. Chem., 2005,3, 2910-2913
Article type
Communication

A C2-symmetric nickel diamine complex as an asymmetric catalyst for enecarbamate additions to butane-2,3-dione

J. S. Fossey, R. Matsubara, P. Vital and S. Kobayashi, Org. Biomol. Chem., 2005, 3, 2910
DOI: 10.1039/B505404D

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