Issue 16, 2005
From the journal:

Organic & Biomolecular Chemistry

Titanocene(ii)-promoted carbonyl allenation utilizing 1,1-dichloroalk-1-enes

Tomohiro Shono,a   Kenji Ito,a   Akira Tsubouchia  and  Takeshi Takeda*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Japan
E-mail: takeda-t@cc.tuat.ac.jp
Fax: +81 42 388 7034
Tel: +81 42 388 7034

Abstract

Treatment of 1,1-dichloroalk-1-enes with Cp2Ti[P(OEt)3]2 produced organotitanium species, which afford allenes on treatment with aldehydes and ketones.

Graphical abstract: Titanocene(ii)-promoted carbonyl allenation utilizing 1,1-dichloroalk-1-enes

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Article information

DOI
https://doi.org/10.1039/B508820H
Article type
Communication
Submitted
22 Jun 2005
Accepted
24 Jun 2005
First published
11 Jul 2005

Org. Biomol. Chem., 2005,3, 2914-2916

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Titanocene(II)-promoted carbonyl allenation utilizing 1,1-dichloroalk-1-enes

T. Shono, K. Ito, A. Tsubouchi and T. Takeda, Org. Biomol. Chem., 2005, 3, 2914 DOI: 10.1039/B508820H

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