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Issue 24, 2005
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Unprecedented use of silver(i) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters

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Abstract

Catalytic diboration of internal and terminal alkenes with Ag(I) N-heterocyclic carbene complexes leads to 1,2-bis(boronate) esters as single intermediates, that can be oxidised towards the corresponding diols.

Graphical abstract: Unprecedented use of silver(i) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters

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Article information


Submitted
04 Mar 2005
Accepted
14 Apr 2005
First published
06 May 2005

Chem. Commun., 2005, 3056-3058
Article type
Communication

Unprecedented use of silver(I) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters

J. Ramírez, R. Corberán, M. Sanaú, E. Peris and E. Fernandez, Chem. Commun., 2005, 3056
DOI: 10.1039/B503239C

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