Intramolecular reduction of the nitro group into phosphoraneimine mediated by a rhenium(V) complex. Synthesis and structure of the novel phosphoraneimine oxorhenium(V) complex [ReOCl{o-(PPh3N)C6H4(NCH2CH2N(CH2CO2H)CH2CO2)}]

M. Allali; E. Benoist; M. Gressier; J. Jaud; N. Habbadi; A. Souizi; M. Dartiguenave

doi:10.1039/B409640A

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Intramolecular reduction of the nitro group into phosphoraneimine mediated by a rhenium(v) complex. Synthesis and structure of the novel phosphoraneimine oxorhenium(v) complex [ReOCl{o-(PPh₃N)C₆H₄(NCH₂CH₂N(CH₂CO₂H)CH₂CO₂)}]

M. Allali,^ab E. Benoist,*^a M. Gressier,^a J. Jaud,^c N. Habbadi,^b A. Souizi^b and M. Dartiguenave*^a

Author affiliations

* Corresponding authors

^a Laboratoire de Chimie Inorganique, EA 807, Université P. Sabatier, 118, route de narbonne, Toulouse cedex 3, France
E-mail: benoist@chimie.ups-tlse.fr

^b Laboratoire de Synthèse Organique et d'Agrochimie, Université Ibn Tofaïl, Kénitra, Maroc

^c CEMES-CNRS, 29, rue Jeanne Marvig, BP 94347, Toulouse cedex 4, France

Abstract

The title compound was synthesised via an unexpected intramolecular reduction of a nitro group in the oxo–Re(V) coordination sphere.

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Article information

DOI: https://doi.org/10.1039/B409640A
Article type: Communication
Submitted: 24 Jun 2004
Accepted: 06 Sep 2004
First published: 16 Sep 2004

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Dalton Trans., 2004, 3178-3180

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Intramolecular reduction of the nitro group into phosphoraneimine mediated by a rhenium(V) complex. Synthesis and structure of the novel phosphoraneimine oxorhenium(V) complex [ReOCl{o-(PPh₃N)C₆H₄(NCH₂CH₂N(CH₂CO₂H)CH₂CO₂)}]

M. Allali, E. Benoist, M. Gressier, J. Jaud, N. Habbadi, A. Souizi and M. Dartiguenave, Dalton Trans., 2004, 3178 DOI: 10.1039/B409640A

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Dalton Transactions