Metal-induced formation of a new chiral bidentate N,O ligand and the synthesis of novel monomeric germylenes

Matthias Driess; Nicoleta Dona; Klaus Merz

doi:10.1039/B411889H

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Metal-induced formation of a new chiral bidentate N,O ligand and the synthesis of novel monomeric germylenes†

Matthias Driess,*^a Nicoleta Dona^a and Klaus Merz^a

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^a Laboratory of Inorganic Chemistry I: Cluster and Coordination Chemistry, Ruhr-University Bochum, Universitätsstrasse 150, Bochum, Germany
E-mail: matthias.driess@rub.de
Fax: +49 234-321-4378
Tel: +49 234-322-4158

Abstract

Lithiation of the N-benzyl substituted diketoamine ligand PhCH₂–N[CH₂C(tBu) [double bond, length as m-dash] O]₂ with lithium diisopropylamide (LDA) affords a novel chiral anionic N,O-ligand L; LiL reacts with GeCl₂·dioxane to give the corresponding new monomeric germylenes LGeCl and L₂Ge.

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Article information

DOI: https://doi.org/10.1039/B411889H
Article type: Communication
Submitted: 02 Aug 2004
Accepted: 26 Aug 2004
First published: 06 Sep 2004

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Dalton Trans., 2004, 3176-3177

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Metal-induced formation of a new chiral bidentate N,O ligand and the synthesis of novel monomeric germylenes

M. Driess, N. Dona and K. Merz, Dalton Trans., 2004, 3176 DOI: 10.1039/B411889H

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Dalton Transactions

Metal-induced formation of a new chiral bidentate N,O ligand and the synthesis of novel monomeric germylenes†

Abstract

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Metal-induced formation of a new chiral bidentate N,O ligand and the synthesis of novel monomeric germylenes

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