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Issue 16, 2004
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Mononuclear nitrogen/sulfur-ligated cobalt(II) methoxide complexes: Structural, EPR, paramagnetic 1H NMR, and electrochemical investigations

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Abstract

The first examples of mononuclear nitrogen/sulfur-ligated Co(II) alkoxide complexes, species of relevance to a reactive intermediate observed for Co(II)-substituted liver alcohol dehydrogenase, have been isolated and characterized by multiple methods including X-ray crystallography, EPR, paramagnetic 1H NMR, and cyclic voltammetry.

Graphical abstract: Mononuclear nitrogen/sulfur-ligated cobalt(ii) methoxide complexes: Structural, EPR, paramagnetic 1H NMR, and electrochemical investigations

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Publication details

The article was received on 01 Jun 2004, accepted on 09 Jul 2004 and first published on 20 Jul 2004


Article type: Communication
DOI: 10.1039/B408177C
Citation: Dalton Trans., 2004,0, 2398-2399
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    Mononuclear nitrogen/sulfur-ligated cobalt(II) methoxide complexes: Structural, EPR, paramagnetic 1H NMR, and electrochemical investigations

    K. J. Tubbs, E. Szajna, B. Bennett, J. A. Halfen, R. W. Watkins, A. M. Arif and L. M. Berreau, Dalton Trans., 2004, 0, 2398
    DOI: 10.1039/B408177C

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