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Issue 16, 2004
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Mononuclear nitrogen/sulfur-ligated cobalt(ii) methoxide complexes: Structural, EPR, paramagnetic 1H NMR, and electrochemical investigations

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Abstract

The first examples of mononuclear nitrogen/sulfur-ligated Co(II) alkoxide complexes, species of relevance to a reactive intermediate observed for Co(II)-substituted liver alcohol dehydrogenase, have been isolated and characterized by multiple methods including X-ray crystallography, EPR, paramagnetic 1H NMR, and cyclic voltammetry.

Graphical abstract: Mononuclear nitrogen/sulfur-ligated cobalt(ii) methoxide complexes: Structural, EPR, paramagnetic 1H NMR, and electrochemical investigations

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Article information


Submitted
01 Jun 2004
Accepted
09 Jul 2004
First published
20 Jul 2004

Dalton Trans., 2004, 2398-2399
Article type
Communication

Mononuclear nitrogen/sulfur-ligated cobalt(II) methoxide complexes: Structural, EPR, paramagnetic 1H NMR, and electrochemical investigations

K. J. Tubbs, E. Szajna, B. Bennett, J. A. Halfen, R. W. Watkins, A. M. Arif and L. M. Berreau, Dalton Trans., 2004, 2398
DOI: 10.1039/B408177C

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