The oxidative addition of a chlorophosphine to Pd0: formation and characterisation of a 42-electron triangulo palladium cluster

Philip W. Dyer; John Fawcett; Martin J. Hanton; D. Michael P. Mingos; Anna-Maria Williamson

doi:10.1039/B408519A

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The oxidative addition of a chlorophosphine to Pd⁰: formation and characterisation of a 42-electron triangulo palladium cluster†

Philip W. Dyer,*^ab John Fawcett,^b Martin J. Hanton,^b D. Michael P. Mingos^c and Anna-Maria Williamson^c

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* Corresponding authors

^a Department of Chemistry, University of Durham, South Road, Durham, UK
E-mail: p.w.dyer@durham.ac.uk
Fax: 0191 384 4737
Tel: 0191 334 2150

^b Department of Chemistry, University of Leicester, University Road, Leicester, UK

^c Department of Chemistry, Imperial College London, South Kensington, London, UK

Abstract

The reactions that lead to the formation of the 42-electron cluster [PdCl{P(NPrⁱ₂)₂}]₃ from various sources of the {P(NPrⁱ₂)₂} moiety are investigated, and the structure of the triangulo cluster confirmed by X-ray crystallography.

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Article information

DOI: https://doi.org/10.1039/B408519A
Article type: Communication
Submitted: 04 Jun 2004
Accepted: 08 Jul 2004
First published: 22 Jul 2004

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Dalton Trans., 2004, 2400-2401

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The oxidative addition of a chlorophosphine to Pd⁰: formation and characterisation of a 42-electron triangulo palladium cluster

P. W. Dyer, J. Fawcett, M. J. Hanton, D. M. P. Mingos and A. Williamson, Dalton Trans., 2004, 2400 DOI: 10.1039/B408519A

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Dalton Transactions