Issue 16, 2004
From the journal:

Dalton Transactions

Crystal synthesis of hybrid organometallic–inorganic hydrogen bonded salts of acid oxoanions

Dario Braga,*a   Marco Curzi,a   Lucia Maini,a   Marco Politoa  and  Fabrizia Grepioni*b  

* Corresponding authors

a Dipartimento di Chimica G. Ciamician, Università di Bologna, Via Selmi 2, Bologna, Italy
E-mail: dario.braga@unibo.it

b Dipartimento di Chimica, Universita' di Sassari, Via Vienna 2, Sassari, Italy
E-mail: grepioni@ssmain.uniss.it

Abstract

Partially deprotonated inorganic oxoanions derived from sulfuric and phosphoric acids have been used to assemble organometallic cations in inorganic–organometallic hybrid systems. The organometallic sandwich cations [(η5-C5H5)2Co]+, [(η5-C5Me5)2Co]+ and [(η5-C5Me5)2Fe]+ have been used because they do not interfere with hydrogen bonding formation forcing self-assembling of the inorganic acids anions HSO4− and H2PO4− into hydrogen bonded mono- and bi-dimensional networks.

Graphical abstract: Crystal synthesis of hybrid organometallic–inorganic hydrogen bonded salts of acid oxoanions

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Article information

DOI
https://doi.org/10.1039/B400667D
Article type
Paper
Submitted
15 Jan 2004
Accepted
18 Jun 2004
First published
08 Jul 2004

Dalton Trans., 2004, 2432-2437

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Crystal synthesis of hybrid organometallic–inorganic hydrogen bonded salts of acid oxoanions

D. Braga, M. Curzi, L. Maini, M. Polito and F. Grepioni, Dalton Trans., 2004, 2432 DOI: 10.1039/B400667D

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