A series of novel Mo(W)/Cu/S heterobimetallic clusters containing SBut− linkages. Synthesis, structure and spectroscopic characterisation
Abstract
Six new copper(I) clusters, [Et4N]2[{MOS3}2Cu4(μ-SBut)2]
(1a: M = Mo; 1b: M = W), [Et4N][{MOS3}2Cu6(μ-SBut)3]
(2a: M = Mo; 2b: M = W) and [Bu4N]2[{MOS3}3Cu9(μ-SBut)3(μ3-SBut)][I]
(3a: M = Mo; 3b: M = W) have been prepared by the reactions of thiomolybdates and thiotungstates with CuSBut under various conditions. The [{MOS3}2Cu4(μ-SBut)2]2− dianions in 1a and 1b represent the first examples of double butterfly-shaped Mo(W)/Cu/S clusters. Addition of more Cu atoms to 1a or 1b resulted in the formation of incomplete double